Skip to main content

Full text of "USPTO Patents Application 10517063"

See other formats


(19) 




JAPANESE PATENT OFFICE 



PATENT ABSTRACTS OF JAPAN 

(11) Publication number: 09085045 A 
(43) Date of publication of application: 31.03.97 



(51) Int. CI B01D 53/68 
B01D 53/34 
B01D 53/54 




(21) Application number 07274821 

(22) Date of filing: 27.09.95 ' 


(71) Applicant: KANKEN TECHNO KK SEIKA 

HIGHTECHrKK 

(72) Inventor: IMAMURA KEIJI 

TSUCHIYA HIROO 


(54) METHOD FOR DETOXIFYING NF3 EXHAUST GAS 



AND APPARATUS THEREFOR 

(57) Abstract: 

PROBLEM TO BE SOLVED: To safely and efficiently 
detoxify NF^ gas so as not to generate environmental 

pollution by adding water and ammonia gas to a gas 
containing NF^ to react them with NF^ to decompose NF^ 

to nitrogen and hydrogen fluoride and neutralizing and 
detoxifying formed hydrogen fluoride as an ammonium 
salt. 

SOLUTION: The NF^-containing exhaust gas from an 

exhaust gas inflow pipe 1 is diluted with the nitrogen gas 
from an inflow pipe 11 to be introduced into an inlet 

scrubber 8 and water is sprayed from above to add v^f^ter 
to the exhaust gas and ammonia gas is added to the 
exhaust gas from an NH^ inflow pipe 6 and this exhaust 

gas is heated by a heater element 5 in a reaction part 2 
and NFg and water are reacted to be reduced and 

decomposed to NOx and hydrogen fluoride. NOx and 
hydrogen fluoride are further reacted with ammonia to be 
decomposed and neutralized to N^, H^O and amrrionium 

fluoride. This heated and decomposed exhaust gas is 
succeedingly introduced into an outlet scrubber 9 to be 
washed *with water and a water-soluble component 
inclusive ammonia fluoride is absorbed, removed and 
detoxified to be discharged from an exhaust pipe 4. 




COPYRIGHT: (C)1997.JPO 



I 



Printed from Mimosa 01/26/04 09:25:37 page -1- 



mB^mffif (jp) <i2) ^ ^ 4^ 1^ ^ ^ (A) (Mmf^mm'Ams^ 

#11^9-85045 

(sDinta* mm^ jfpi^mn fi sfi^s^ 

B 0 1 D 53/68 B 0 1 D 53/34 1 3 4 C 

53/34 ZAB ZAB 

. 53/54 1 2 8 



S®E»:Si W:*53So»2 FD 3 M) 





4$HT7 -274821 




592010106 










(22)tUB!B 






*R&?>CBaT^*»r 3 T B18# 9 






(TDtURA 


395017139 
















:*:ETtr*5^K4fcS4TB 7S28^ 
















:*:E«5fB5cBa*^ar3TBi8#9^ 














(72)|g§^ 
























(74)f^ffiA 


^39± 



(54) NF3«^:tfx<0liSt$:;&^RCfli|^{B 



(57) [SiK)] 




13 



(2) 



«M¥9-8 5 0 4 5 



scit*i^att-^NF3»*-xa)»ssBo ' 

[000 1] 

l^^±■r^NF3g^:b•xa)KtS:»^^XU:f»SaSlcB|■r ' 

[O O O 2] 

-So 

[0 0 0 3] NFzi^mt^:f5}^tLX{t. (a) N F3 

$-y-r^S^^:;^,^(i^gB¥3— 652i8^^i^«). (b) n F3 

±m^tN H3<!: ^Si£:3?'y-'5*a(*#ll8^4— 290524# 

[0 0 0 4] LA^L^^:A<t». ±t^(a)(Dyj^v{t. mm 

1*1 f*K^bllfflar- fe a^) •^^trcge'r iS:t c ^ 

S i: -r ^ i: 5 Fp^H^ A<fc^o 
[0 0 0 5] 

[0 0 0 6] 

[iSS*«^-r-5f::Ar)(7)¥©] *^B^#f,|i. N F3^ 



N F3/)<SSi:37*v^b*Sl::5^«*4x. *fi£Lfr^ 
•v<b*«ST>^-';7Affli:LT*Sl. f»S-r*Citfc 
c^y. ffi^cfey ;!)^•^NOx(Dil)*t^^:<NF3 
/><«SibSFtT.^C<t^mti5L. *»BJ^^j5£L/--o 10 

^fg^cD^gli. N F3^^^-r^m{*i^. yi^tr 

ft. f»S'r^::t^i^at-r'SNF3s^#x(D^s?^ 

[0 0 0 7] :*:SgBJ|c^SL^r(i. N F3l*7K<^JSf5L 
S(2N F3+3H20^NO + N02+6H F)o ^w^C 

±f&Ltzy-jityi<smity>=e-rt^i^Lxy-^it7:y 

ix-SCN F3+NH3->N2+3 H F)o 
[0008] 

im^oum uiT. :$imM(oy3mk<^xsmm:iz'z>i^x 

[0 0 0 9] *^BJlCfcL^•Cli. N F3^*l*:^*XfC7K 

^^mj&t^o ^*o-c. isai^fF^jifessit^eWT'NF 

3SJe * 1 vo I %JaT. L < \tO. 5vo I %]5iTlc <f cfc 

[0010] g^**X35Ag(1)<fcy«A*nfcNF3^^ 
«^:^*Xfi. N25SA^(11):6N^<DMm:b*XT*4&^;^tL 

L. ±gP<*:y7K*faSLr**X<!:Jf®$-t±-5»fCci:y. 

F3M<tit«-r^A<. jl«NF3(0 2f&^;u>a-t;&<»^L 

[00 1 1] CZ-CRlrSfi(7>7KS^*DS?+lfcSf#X(*. 
N H 335 A® (6) N H 3:^"X ^ ^iin ^ HT . JSfC^aS (2) 

*i:SJ5LrNOxi::7'><b*mjcS7c53^fl?$tt^o T 

HF2tS^lfNF3t7i(it(D^lt± 

f&i!^(Dmizitm-r^t<^ fi«NF3CD4fg^;ujaJi;&<$? 

[0 0 12] *^B^T'ffll^^Si£a5(2)<^: LTIi^irlS . 
JSaffi(*ii»300*'C-700'*C. $ibl::»^L<l*. 450**C 




[0 0 13] SIC. NOxfccfct;:7'vib7KSEliT>^- 

7i:SCt;LTN2. H2O. Z? vitT :y'^=-'yJx\Zi^m. 

[0 0 14] .^iP*l**S7Kg(7)3b>t>7ka*4»>^(3)lc\ 
7K>:/(iO)-ei)Di±^ti. Aax^7/<-(8) 

fc<J:i;tiiP;j^^^/<-(9)<Dji&7Ki:<>:'5>o APXi:7^/'v 

I*. 7K25t7K^>^{3)*<D7Kr•+«l**^»*e(13);5^^, 
[0 0 1 5] 

[HffiffH] 

[SIffiClJl ]g^:t^Xg!Ag(l)i:I'J10vo|o^CDN Fa^^t 
Sife^S'j*:/ h;U/»T% N25KA1(ll)cfcyM^^250'j 
h;u/»r*^ix^tLAP;^<7^/<-(8)|c3SAL. tK* 

ir. NH3;•^EA'S(6)7^)^^>NH3:^*X^. 10U *v h;^/5^'T' 




^^88^9-8 5 04 5 

5«?-CSi£*-a-/co JSfE^(0*';^liaiPX^^/\— (9) 
Vik^Ltzo aiP**X*<DN F3**X;Bffil*5ppm. NO 
X;a)S(*3ppnHslT. 3?'vib7K*affitt0. 5ppmiaT-C 

[0 0 16] [||Jfefitj2]N Fa^JKll. 5vol%#t;CV 

(Dc^iy^A-r-sjanii. Hffiijqi ^(^i:^#-r:5&sL 

tzo aiP:^'X*<7)N F3:^-ASS(i8ppm. NOxSSli 
SppmJaT. 37'>^b7K*;BSl*0. 5ppniJaT"efcofro 
[0 0 17] 

[^B-flCDSfi^] *^B^lc<fcy. ltSW«;^T:% L;^)^t^ 

^raT?NF3(7)5^«A<prfig4?:3sy. n ox<oi!]^-^^ga) 

[@@a>ffim^ci:S!B^] 

[HI] *^e«f3j:^N F3Sf^-X(7>l»WSM(D«ES^ 



(1) 




(2) 




(3) 




(4) 




(5) 




(6) 




(7) 




(8) 




(9) 




(10) 




(11) 




(12) 




(13) 





] 

4